Another use is enhancing saturation of an image. My DLP projector has a mode like this to take advantage of its 6 primaries. Enhancing saturation can produce a convex gamut even from a non-convex one (e.g. sRGB), the only means of reproducing of which may be with additional primaries.
By my estimation, the main problem with Quattron wasn't that it had a 4th primary, which is legitimately useful. It's that - as you point out - it didn't. It literally did not have a yellow primary; just a yellow filter illuminated by the red and green primaries. Thats, like, total hokum.