I really like Python's design here, if we are not talking about full on language features to enforce immutability, where functions that mutate never return a value and are named with verbs (e.g. 'sort()'), while functions that don't mutate return their value and are named with adjectives (e.g. 'sorted()'). This feels natural - mutations are actions, while pure functions are descriptions.
The only real downside is the lack of return values mean you can't chain mutations, but personally that never bothered me.