The first part of the statement (at least one obvious way to do it) goes to gaining a lot of expressive power from having learned only a subset of the language specification corresponding to the most important concepts. So you invest only a small amount of time in wrapping your head around only the most important/basic language concepts and immediately gain the power that you can take any thought and express it in the language and end up not just with some way of doing it, but with the right/preferred way of doing it.

The second part of the statement (at most one obvious way to do it) makes it easy to induce the principles behind the language from reading the code. If you take a problem like "iterate through a list of strings, and print each one", and it always always always takes shape in code by writing "for line in lst: print( line )" it means that, if it's an important pattern, then a langauge learner will get exposed to this pattern early and often when they start working with the language, so has a chance to quickly induce what the concept is and easily/quickly memorize it due to all the repetition. -- Perl shows how not to do it, where there are about a dozen ways of doing this that all end up capable of being expressed in a line or two. -- Therefore, trying to learn Perl by working with a codebase that a dozen people have had their hands on, each one preferring a different variation, makes it difficult to learn the language, because you will now need to know all 12 variations to be able to read Perl reliably, and you will only see each one 1/12th as often making it harder to memorize.