Libra maintains "100% reserves." How is that money reserved? For a bank, it needs to be either in cash in the vault or on deposit with the Federal Reserve. Either way it's not getting loaned out again. Presumably Libra will be depositing it at (loaning out to) a bank, or putting it in short term bonds, money market, etc. Either way, they're loaning out all of the money, i.e. they have a 0% reserve.
What Facebook is proposing is merely to have assets equal to the deposited funds. For a bank, that is called teetering on the edge of insolvency. If a bank's assets ever dip below its liabilities, it is insolvent and either has to raise equity capital or be wound down by the government. This is why banks have capital requirements, so that they have a buffer against loans going bad.