I'm 33 and didn't grow up in a radio culture either. I first heard of podcasts around 2006 in college when Apple came out with a mic dongle for the iPod. Never bothered checking any out. It was only when I came across a lengthy interview with an athlete I like that I started listening. Podcasts can be good for that, since TV usually focuses on short segments to fit in all the commercials.
For me, podcasts aren't like TV shows where I feel connected to the cast members. I'll listen only if the guest is interesting. In rare cases, I'll subscribe if the format is interesting, e.g. bad movies reviewed by comedic actors.