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From Webkit.org, June 7, 2017 [1]:
>Today we are thrilled to announce WebKit support for WebRTC, available on Safari on macOS High Sierra, iOS 11, and Safari Technology Preview 32. In this post, we will go through an overview of our implementation. We will have future posts that cover more best practices for developers.
[1] https://webkit.org/blog/7726/announcing-webrtc-and-media-cap...
For PWAs, you need Service Workers and some accompanying APIs and Safari seems to have those as well: https://webkit.org/blog/8090/workers-at-your-service/