Yes, solar seems like it will continue to drop in price and you'd probably want to leverage that savings too.
A mass produced portable compressor unit could also be neat. Something for around the home. A 1kw to 3kw unit could be nice to make dry ice. You practically need to have AC if you want to work in Florida or other tropical climate. There is a big market for AC combined with solar in the U.S. since folks want AC and a good chunk probably also want to use solar. Given that you want cooling at night, a solar powered dry ice maker might be able to compete with solar + battery + AC. The panels can feed directly into the compressor to make the night's dry ice rather than storing the energy in a battery and running the compressor at night.
The bonus is that any efficiency gains in the dry ice maker could be applied to processes further down stream that make methane or heavier hydrocarbons. You get a solar cooling solution and something that could be helpful when bootstrapping synth gas production.
Here are some small high pressure projects / products:
Liquid nitrogen
https://makezine.com/2010/06/07/diy-liquid-nitrogen-generato...
Shoebox compressor
https://www.shoeboxcompressor.com/
Not sure how you'd separate the CO2 out of the liquid air though.