I'm aware it was used in Visual Studio, and oh, the Expression Studio suite [0] – another discontinued line of great products, for making stuff with WPF – but that's all I can remember.
Not even Calculator or Notepad used WPF as far as I know, which would have been the simplest apps to port and could have bolstered developer confidence in the technology (the point of this whole discussion.)
And why is it "was"; does VS now not use WPF?
[0] https://en.wikipedia.org/wiki/Microsoft_Expression_Studio