The easiest way to understand it is to look at the question from a philosophical framework where it makes no sense to claim that there are "more" irrationals than rationals. And then untangle why it came to a different answer.
In Constructivism, all statements have 3 possible values, not 2. They are true, false, and not proven. All possible objects must have a construction. So instead of talking about a vague "Cauchy sequence", we might instead have a computer program that given n will return a rational within 1/n of the answer.
The first thing to notice is that all possible things that could exist is contained within a countable set of all possible constructions. There can't be "more" irrationals than rationals.
But what about diagonalization? That proof still works. You still can't enumerate the reals. But why not? The answer is because determining whether a given program represents a real is a decision problem that cannot in general be solved by any algorithm. You are running into the same category of challenges that lie behind Gödel's theorem and The Halting Problem. It is not that there are "more" irrationals than rationals. It is that there are specific programs which you can't decide whether they represent reals.
From a constructivist's eyes, the traditional proof that there are more irrationals falls apart because you're reasoning about unprovable statements about arbitrary sequences whose logic could have been constructed with the same sort of logic that you're applying to them. Is it any wonder that you wind up concluding the "existence" of things that clearly don't actually exist?
Now stepping back from BOTH philosophies, the differences between them lie in different attitudes about existence and truth. Attitudes that underly the axioms which we use, and cannot possibly be proven one way or another. (Gödel actually proved that. Any contradiction in Constructivism is immediately a contradiction in classical mathematics. But conversely there is a purely mechanical transformation of any proof in classical mathematics which resulted in a contradiction, into a constructive proof that also results in a contradiction.)