That's all true, but I think we're talking past each other a bit. My point isn't about what mechanics would be used or the type of memory order specified (that's the irrelevant part), but merely to highlight that this could use more attention in the docs. The atomic used may be viewed as a "lint" to a reader/user that something interesting may be going on with how this type is used - similar to how *mut isn't automatically Sync; it's an opportunity for people to pause and think things through. If you're looking at a type absent of any atomics or concurrency primitives, it's not apparent that it may be used like that (particularly since Sync is auto-derived and doesn't appear in the source code of the type).
I know one can look at this as being unimportant because only unsafe code that works with Sync types carries the burden of upholding the invariants. But, I still contend that memory ordering ought to be discussed, somewhere, while there's no official memory model documentation (not even sure that's in the plans, although I feel like I may have come across a github issue for that).
Anyway, I don't think I'm saying anything new in this reply over my others. If you feel existing docs are adequate in this regard, that's fine - we can agree to disagree :).