Kivy would probably be an easier path than Toga. It incorporates pyjnius which you would need to solve the wifi scan on android, and already has the UI part figured out.
My laptop can see 26 unique wifi hotspots (other people in the building, cafe across the street, etc), which is the number the author was referring to.
[1]: https://news.ycombinator.com/item?id=11517667
[2]: https://github.com/schollz/find
Its good enough to see if somebody is in a meeting room and unavailable or if they are probably free.
If you have more than one device on the network that belongs to one person, it uses the device that has been connected to an AP for the least time (theoretically that's the last one that moved)