S3 is not a monolithic architecture, Amazon is a strong proponent of Service Oriented Architecture for producing scalable platforms.
There are a number of services behind the front end fleet in S3's architecture that handle different aspects of returning a response. Each of those will have their own code paths in the front end, very likely developed by different engineers over the years. As ever, appropriate status codes for various circumstances are something that always seems to spur debate amongst developers.
The change in status code would likely be a reflection of the various components entering unhealthy & healthy states, triggering different code paths for the front end... which suggests whatever happened might have had quite a broad impact, at least on their synchronous path components.