It's been estimated that if the universe were a computer, it could have performed no more than 10^120 operations on 10^90 bits of data so far (based on the size, age, and total energy of the known universe).
http://arxiv.org/abs/quant-ph/0110141 I think the number of physically relevant bits of pi would be represented in there somewhere. But there's a long road ahead. If the universe keeps "computing" forever, the precision of numbers involved could also keep growing.