A mediocre answer that was posted one minute after the question was submitted often has more votes than a well thought answer posted several hours later.
A better solution might be to randomly order answers, regardless of votes, for the first couple of hours (maybe even day). This will further help remove any ordering bias.
I also feel that authors of answers should be hidden for the first couple of hours (or day). Just because John Resig answered a question, doesn't necessarily mean it's the best response.