In which way? node[1] means the second child.
If you mean node[x] returns node.attrib.get(x) when x is a string, and the nth-child when x is an integer, then I think that puts too much complexity into the API.
If you mean stay with the existing node.attrib dict-like API, then node@name is a simple shortcut for node.attrib.get(name), but it's 1) more aligned with CSS/XSL '@' notation for attribute syntax, and 2) faster in CPython.
(Just realized that '/' and '//' also make sense in that context. node / "abc" / "xyz" @ "p" would be the child "abc"'s child "xyz"'s attribute "p". Perhaps my proposal is a bad idea because it might suggest that these other forms are allowed.)